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Even if they did, their legal credentials would not have been of much use in the process, so what's the purpose of this question?
No one is addressing the question. Which NLU grads have founded their startups (not law firms obvs) and become millionaires (as in, hundreds of crores in the bank, private jet, multi-crore houses in London, NY, Mumbai etc)????

Answer: Probably no one
If millionaire means having multiple millions (10 lakh=1 million) in your account, then all of them will qualify. So will a large number of lawyers working in law firms (every tier one firm partner for sure).
RAMANUJ MUCKERJEE. Founder of Law Sikho. He is a millionaire now.

I don't know if the others mentioned are millionaires, though Sachin Malhan perhaps is.
Again goes to show your lack of knowledge about reality and the industry. Other than the people named, there are also the likes of Shishira Rudrappa, Ashish Arun and others.
Lots from NLS alone. Naiyya Saggi. Sachin Malhan. Mathew Chandy. Sameer Singh.

Lots of others have started their own law firms (which arguably needs entrepreneurial skills) and have done very well for themselves.