Hi,
Can you guys suggest some good companies I can apply to start a career as an in-house lawyer?

Hindalco Industries Limited.

not any which pay enough for sustenance, start out at a firm

Fortunately, you are bit mistaken

Vedanta

ICICI Bank

ITC. ONGC. SAIL. Star. Infosys and Wipro. Mindtree. SBI.

Wipro but mostly through campus recruitment

How do you apply to these companies? Through the career page on their websites? (Which is confusing) or by connecting with their legal head on LinkedIn?

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Startups are hiring on LinkedIn