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Put bread on your table right now. You can move later easily if what you are saying is true as to how great you are.
Keep the PPO. Make a lateral move later- or do your callbacks and reject this PPO when you have another one secured.
Is it possible to get a PPO and keep interning for a better offer, if yes, please do.

Looks like your firm is SRL
Hi, OP here. That was another part of my question, how should I go about it? What if the HR finds out, and how do I reject without offending the partner who has made an effort to ensure I get the PPO in the first place?
You can switch in some months, having a job right out of college is important. Don't let this go.