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1. Basic reading of accounts and interpretation is more than sufficient. You don't need to learn 'Accounts' beforehand. You will learn it on the job.

2. No, you don't need to be 'good' at math for Capital Structure. Basic knowledge is more than sufficient, you will need basic arithmetic skills (Class 7-8).

Read:
SEBI ICDR - Regulation 1 to 45 and Schedule VI;
SEBI LODR - Regulation 14 to 32;
Companies Act, 2013.

P.S - Please consider this practice for initial years only, earn some money, move to a better practice area.